Carbon-carbon cross coupling catalyzed by transition metals...

C - Chemistry – Metallurgy – 07 – D

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C07D 265/18 (2006.01) B01J 21/00 (2006.01) B01J 23/00 (2006.01)

Patent

CA 2546352

The present invention provides methods of coupling carbon-containing compounds using a transition metal or transition metal complex on a solid support. The solid support can include alkaline earth metal salts, including carbonate and sulfate salts. The transition metals can include palladium or nickel metal. The method can include combining two carbon containing compounds and a transition metal or transition metal complex on a solid support in the presence of a solvent, desirably an alcohol.

La présente invention concerne des procédés de couplage de composés contenant du carbone à l'aide d'un métal de transition ou d'un complexe de métaux de transition sur un support solide. Le support solide peut comprendre des sels métalliques terreux alcalins, y compris des sels de carbonate et de sulfate. Les métaux de transition peuvent comprendre le palladium ou le nickel. Le procédé consiste à combiner deux composés contenant du carbone et un métal de transition ou un complexe de métaux de transition sur un support solide en présence d'un solvant, de préférence un alcool.

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