Carbonate-supported catalytic system for epoxidation of alkenes

Details Carbonate-supported catalytic system for epoxidation of alkenes Carbonate-supported catalytic system for epoxidation of alkenes

B - Operations, Transporting

01

J

260/372, 252/85

B01J 32/00 (2006.01) C08F 4/02 (2006.01)

Patent

CA 1282772

Abstract: A process is provided for epoxidation of an alkene in the presence of an oxygen-containing gas comprising contacting the alkene and the oxygen- containing gas under epoxidation conditions in the presence of at least one gaseous efficiency-enhancing member of a redox-half reaction pair and a solid catalyst, the catalyst comprising a catalytically- effective amount of silver on a solid porous support and an efficiency-enhancing amount of at least one efficiency-enhancing salt of a redox-half reaction pair, the support comprising at least one carbonate salt selected from the group of carbonates of cations consisting of barium, strontium, calcium, magnesium, and mixtures thereof.

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