Carbonylation of allylic ethers to esters

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

260/485.3

C07C 67/37 (2006.01) B01J 27/13 (2006.01) C07C 69/587 (2006.01)

Patent

CA 1280120

ABSTRACT OF THE DISCLOSURE A method is disclosed for the production of esters by reaction of an allylic ether with carbon monoxide in the presence of a catalytically effective amount of a Group VIII noble metal catalyst and halide compound to obtain esters. The halide compound is present in an amount sufficient to prevent the catalyst from being converted into a Group VIII metal during the reaction. When the reaction is conducted in the presence of a quaternary ammonium salt the ester may be extracted by solvent extraction to minimize catalyst decomposition caused when extractive distillation is used to separate the ester.

519191

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