Carbonylation of conjugated dienes

C - Chemistry – Metallurgy – 07 – C

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C07C 69/533 (2006.01) C07C 51/14 (2006.01) C07C 57/03 (2006.01) C07C 67/38 (2006.01)

Patent

CA 2099192

T 1848 A B S T R A C T CARBONYLATION OF CONJUGATED DIENES The invention relates to a process for the preparation of an alkenoic acid derivative by reaction of an aliphatic conjugated diene with carbon monoxide and a hydroxyl group-containing compound in the liquid state in the presence of a catalyst system comprising a palladium compound, a multidentate phosphine ligand, and optionally a protonic acid, wherein the reaction is conducted in a reaction medium of controlled polarity. VM7/T1848FF

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