Carbonylation process

Details Carbonylation process Carbonylation process

C - Chemistry, Metallurgy

07

C

260/466.9

C07C 69/96 (2006.01) B01J 31/30 (2006.01)

Patent

CA 1137104

RD-10,733 ABSTRACT OF THE DISCLOSURE A carbonylation process which comprises contacting a .beta.-fluoralkanol with carbon monoxide and a Group VIIIB element selected from ruthenium, rhodium, palladium, osmium, iridium,or platinum having an oxidation state greater than zero. The resulting .beta.-fluoroaliphatic carbonates can be employed in combination with alkanols and/or phenols to prepare aliphatic and aromatic mono- and polycarbonates. The resulting carbonates are useful in a wide variety of applications, especially polycarbonates which can be molded or formed into films, sheets, fibers, laminates, or reinforced plastics by conventional techniques.

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