Carboxylic acid ester homologation using a sulfided nickel...

Details Carboxylic acid ester homologation using a sulfided nickel... Carboxylic acid ester homologation using a sulfided nickel...

C - Chemistry, Metallurgy

07

C

260/495.1

C07C 67/36 (2006.01) C07C 29/32 (2006.01) C07C 69/14 (2006.01) C07C 69/24 (2006.01)

Patent

CA 1224487

ABSTRACT OF THE DISCLOSURE A process for the conversion of carboxylic acid esters to homologous carboxylic acid esters which comprises reacting a carboxylic acid ester having from two to about twenty carbon atoms with hydrogen and carbon monoxide in the presence of a heterogeneous sulfided cata- lyst comprising nickel or cobalt, optionally in admixture with a co-catalyst selected from the elements of Group VI-B of the Periodic Table.

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