Catalysis in hydroformylation

Details Catalysis in hydroformylation Catalysis in hydroformylation

C - Chemistry, Metallurgy

07

C

260/573.2

C07C 47/02 (2006.01) C07C 45/50 (2006.01)

Patent

CA 1102823

ABSTRACT OF DISCLOSURE This invention relates to catalytic hydroformylation reactions, for example the hydroformylation of internal olefins. In particular the invention relates to a process for the production of a straight chain aldehyde from an olefin comprising reacting the said olefin in a liquid reaction medium with hydrogen and carbon monoxide at a total pressure of less than 500 psig in the presence of a complex of Rh(1) in solution in the said medium and a homo- geneous co-catalyst dissolved in said reaction medium comprising a co-ordination complex of a transition metal other than rhodium selected from Group 6 or Group 8 of the Periodic Table The transition metal is, preferably, selected from the group consisting of Cr, Mo, W, Fe, Co, Pd, Pt and Ru.

305731

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