Catalyst and method for the synthesis of chlorine dioxide

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B01J 23/38 (2006.01) A61L 2/20 (2006.01) A61L 12/10 (2006.01) B01J 23/52 (2006.01) B01J 27/232 (2006.01) C01B 11/02 (2006.01) G02C 13/00 (2006.01)

Patent

CA 2143981

Chlorine dioxide is generated from an aqueous solution of sodium chlorite in the presence of a catalyst having a reduced rate of deactivation. The catalyst is preferably palladium, or palladium together with another platinum group metal (e.g., Pd+Pt), or palladium together with a Group IB metal? (e.g., Pd+Au) deposited on a support modified by Group IA carbonate salt (e.g., K2CO3) or a Group IIA carbonate salt (e.g., CaCO2) or a magnesium salt that can be converted to MgO or a support consisting of a Group IA carbonate salt or a Group IIA carbonate salt or a magnesium salt that can be converted to MgO.

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