C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
402/551, 252/93.
C08F 4/02 (2006.01) C08F 4/16 (2006.01) C08F 4/20 (2006.01) C08F 10/00 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)
Patent
CA 2036767
Case 7479(B214) (2) ABSTRACT OF DISCLOSURE CATALYST AND PREPOLYMER USED FOR POLYMERISING OLEFINS, AND (CO-)POLYMER OF ETHYLENE OBTAINABLE THEREFROM The present invention relates to a solid catalyst suitable for polymerising olefins in a heterogeneous process, the catalyst being obtainable by a process comprising in a first stage contacting an electron-donor D2 containing labile hydrogen, e.g. alcohol, with a spheroidal MgCl2 support containing an electron-donor D1 free from labile hydrogen, e.g. ether, and in a second stage contacting the resulting support with a zirconium metallocene, at least one titanium or vanadium halide and optionally with an organoaluminium compound, preferably an aluminoxane. The solid catalyst may be used as such or in the form of a prepolymer in a polymerisation of olefins, the prepolymer being obtained by contacting the solid catalyst with ethylene or a mixture of ethylene with C3 to C8 alpha-olefin in the presence of an organo-aluminium compound, preferably an aluminoxane. The solid catalysts and the prepolymer consist of spheroidal particles preferably having a narrow particle size distribution.
Bailly Jean-Claude Andre
Chabrand Christine Jacqueline
Bp Chemicals Limited
Fetherstonhaugh & Co.
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