Catalyst and process for dehydrating 2-alcohols

Details Catalyst and process for dehydrating 2-alcohols Catalyst and process for dehydrating 2-alcohols

B - Operations, Transporting

01

J

252/54, 260/692,

B01J 23/00 (2006.01) B01J 23/10 (2006.01) B01J 23/12 (2006.01) C07C 1/24 (2006.01) C07C 11/113 (2006.01)

Patent

CA 1189848

Abstract of the Disclosure Novel catalysts are disclosed for the selective dehydration of 2-alcohols to .alpha.-olefins. In one case, the catalyst comprises at least one catalytic metal oxide on a low surface area aluminum oxide-containing support. In another case, the catalyst comprises a mixture of thorium oxide and cerium oxide on a base treated aluminum oxide containing support. There is also disclosed a novel process for obtaining high purity 4-methyl-1-pentene involving the dehydration of 4-methyl-2-pentanol followed by disproportionation with ethylene.

420812

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