Catalyst and process for reducing carbon monoxide

B - Operations – Transporting – 01 – J

Patent

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252/63.B, 260/67

B01J 23/70 (2006.01) B01J 23/745 (2006.01) C07C 1/04 (2006.01)

Patent

CA 1073436

ABSTRACT OF THE DISCLOSURE: Reduction of carbon monoxide by means of hydrogen with the resultant formation of a mixture of hydro- carbons having substantially from 1 to 4 carbon atoms in contact with a catalyst containing iron or a mixture of iron and copper as its catalytically active ingredient, the catalyst being made by contacting one or more complex salts of the following general formula: Mex [Fe(CN)6]y in which Me stands for an iron and/or copper-ion, x stands for a number of 1 to 4, and y stands for a number of 1 to 3, with hydrogen or a hydrogen/carbon monoxide-mixture at about 200 to 500°C, under 1 to 100 atmospheres absolute and over a period of about 2 to 20 hours and thereby reducing the complex salts substantially to elementary iron or copper.

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