C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
252/109, 402/381
C08F 10/02 (2006.01) C08F 4/645 (2006.01) C08F 4/655 (2006.01)
Patent
CA 1334405
A solid catalyst component for the low-pressure polymerization of ethylene and C3-C10 alpha-olefins into very high molecular weight polyolefins is in the form of a spherical granular solid having a surface area of between 20 and 40 m2/g, a mean pore radius of between 5,000 and 40,000 A and a porosity of between 40 and 90 vol %, and is definable by the following formula (in atomic proportions): X (1), Mg (1-8), Al (0.2-0.8), Cl (5-20), (Et+OEt+OR) (1-3); where: X = Hf or Zr; Et = ethyl group; OEt = ethoxy group; and OR = alkoxy group containing from 2 to 8 carbon atoms in the linear or branched alkyl portion. Such a catalyst component is obtained by preparing a solid spherical granular support by spray-drying an ethanolic solution of magnesium chloride, reacting said support with a hafnium or zirconium alkoxide or halogenalkoxide, and finally reacting the thus treated support with an alkyl aluminium chloride.
610417
Barazzoni Lia
Ferrero Cesare
Invernizzi Renzo
Malquori Stefano
Masi Francesco
Enichem Anic S.p.a.
Robic
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