Catalyst composition and process for oligomerization of...

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B01J 31/18 (2006.01) B01J 31/14 (2006.01) C07C 2/36 (2006.01) C07F 9/46 (2006.01)

Patent

CA 2703021

The present invention relates to a catalyst composition comprising: (a) a binuclear chromium(II) complex; (b) a ligand of the general structure (A) R1R2P-N(R3)-P(R4)-N(R5)-H or (B) R1R2P- N(R3)-P(R4)-N(R5)-PR6R7, wherein R1, R2, R3, R4, R5, R6 and R7 are independently selected from halogen, amino, trimethylsilyl, C1- C10-alkyl, aryl and substituted aryl, wherein the PNPN- or PNPNP-unit is optionally part of a ring system; and (c) an activator or co-catalyst, as well as to a process for oligomerization of ethylene.

La présente invention concerne une composition de catalyseur comprenant : (a) un complexe de chrome(II) binucléaire ; (b) un ligand de structure générale (A) R1R2P-N(R3)-P(R4)-N(R5)-H ou (B) R1R2P-N(R3)-P(R4)-N(R5)-PR6R7, dans lesquelles R1, R2, R3, R4, R5, R6 et R7 sont indépendamment choisis parmi un atome d'halogène, un groupe amino, triméthylsilyle, alkyle en C1-C10, aryle et aryle substitué, l'unité PNPN ou PNPNP faisant, en option, partie d'un système cyclique ; et (c) un activateur ou un cocatalyseur, ainsi qu'un procédé d'oligomérisation d'éthylène.

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