Catalyst composition, method for producing same and method...

C - Chemistry – Metallurgy – 08 – F

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252/104, 402/631

C08F 4/78 (2006.01) B01J 31/18 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1084480

ABSTRACT OF THE DISCLOSURE Supported catalyst compositions incorporating preformed materials comprising the reaction product of organophosphorus compounds such as the organophosphates and organophosphites with chromium trioxide, wherein the organic moiety is a hydrocarbon radical, e.g., alkyl, aralkyl, aryl, cycloalkyl, or the like or combinations thereof. Typical supports constitute an inorganic material of high surface area, especially a high pore volume (> 1.96 cc/g) silica xerogel. Catalytically promoted polymerizations of 1-olefins proceed efficiently to products of specially adapted utility for molding, and particularly the production of blow molded articles. The polymerization activity of the catalyst compositions is promoted by heating in a dry, oxygen containing atmosphere. The catalysts are utilized alone or in conjunction with other catalytic ingredients such as organometallic and/or organo non-metallic reducing agents.

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