Catalyst for halogen exchange in halohydrocarbons and for...

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B01J 21/04 (2006.01) B01J 31/02 (2006.01) B01J 37/22 (2006.01) C07C 2/86 (2006.01) C07C 5/23 (2006.01) C07C 11/02 (2006.01) C07C 17/20 (2006.01) C07C 19/08 (2006.01)

Patent

CA 2034848

ABSTRACT Z/QM 35584Z A CATALYST FOR HALOGEN EXCHANGE IN HALOHYDROCARBONS AND FOR ACID/BASE REACTIONS A catalyst for halogen exchange in halohydrocarbons or for acid/base reactions comprising a halogenated gamma-alumina having a hydrocarbonaceous or halohydrocarbonaceous material laid down thereon. The catalyst is prepared by halogenating gamma-alumina with SF4, SOF2, COF3 COCl3 or CCl4 and conditioning the halogenated alumina with a gaseous olefin or a halohydrocarbon to lay down a hydrocarbonaceous or a halohydrocarbonaceous material on its surface. The catalyst is useful for producing fluorohydrocarbons or chlorofluorohydrocarbons by reacting HF with halohydrocarbons under mild conditions.

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