Catalyst for polyisocyanurate foams made with alternative...

C - Chemistry – Metallurgy – 08 – G

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C08G 18/18 (2006.01) B32B 5/18 (2006.01) C08G 18/42 (2006.01) C08G 18/81 (2006.01) C08J 9/14 (2006.01)

Patent

CA 2108849

ABSTRACT Rigid, closed cell polyisocyanurate foams are prepared by reacting together a polyisocyanate and a polyester polyol or a mixture of a polyester polyol and at least one other isocyanate-reactive compound in the presence of (a) a hydrogen-containing blowing agent or a mixture of a hydrogen-containing blowing agent and at least one co- blowing agent and (b) a catalyst mixture comprising (i) a carboxylate salt of an alkali metal or an alkaline earth metal or mixtures thereof, (ii) a tertiary amine, and (iii) a quaternary ammonium carboxylate salt, wherein the equivalent ratio of carboxylate metal salt: tertiary amine is a value less than about 2:1, and the quaternary ammonium carboxylate salt is present in an amount which enhances the char structure of polyisocyanurate foams made with the catalyst mixture and subjected to flammability char tests.

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