Catalyst for reducing carbon monoxide

B - Operations – Transporting – 01 – J

Patent

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252/45, 252/63.B

B01J 21/12 (2006.01) B01J 23/72 (2006.01) B01J 23/74 (2006.01) B01J 23/745 (2006.01) B01J 37/00 (2006.01) C07C 1/04 (2006.01)

Patent

CA 1084894

ABSTRACT OF THE DISCLOSURE A catalyst containing iron or a mixture of iron with copper as its active ingredient, made by preci- pitating a complex salt of the general formula: Mex[Fe(CN)6]y in which Me stands for an iron and/or copper ion, x stands for 1, 2, 3 or 4, and y stands for 1, 2 or 3; separating and drying the precipitated salt, and reducing the salt by contacting it with at least stoichiometric proportions of hydrogen or a mixture of hydrogen and carbon monoxide, for use in the re- duction of carbon monoxide by means of hydrogen with the resultant formation of a mixture consisting sub- stantially of C1-C4 hydrocarbons is modified. The modified catalyst is formed a) by subjecting the precipitated and dried salt to thermal decomposition at a temperature of 200 to 500°C in the absence of hydrogen or a mixture of hydrogen and carbon monoxide, or b) mixing the precipitated and dry salt with a carrier, tabletting, pelletizing or extruding the resulting mixture and reducing it by means of hydrogen or a mixture of hydrogen and carbon monoxide, or c) mixing the precipitated and dry salt with a carrier, tabletting, pelletizing or extruding the resulting mixture and thermally decomposing it at 200 to 500°C in the absence of hydrogen or a mixture of hydrogen and carbon monoxide.

291145

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