Catalyst for the direct conversion of methane to higher...

B - Operations – Transporting – 01 – J

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B01J 23/34 (2006.01) B01J 37/02 (2006.01) C07C 2/84 (2006.01) C07C 5/32 (2006.01) C07C 9/06 (2006.01) C07C 11/04 (2006.01)

Patent

CA 2062349

91-451 ABSTRACT A method for preparing a catalyst for conversion of methane to higher hydrocarbons, discloses the steps of: forming a mixture of a manganese aqueous solution and an oxidative agent aqueous solution in an inorganic oxide support material; varying a pH value of the mixture between acidic and basic values to obtain a precipitate of manganese oxide; drying the manganese oxide precipitate; impregnating the dried manganese oxide precipitate with a promoter to obtain an impregnated solid; drying the impregnated solid; and calcining the impregnated solid until a surface atomic ratio of promoter to manganese is at least 5. The catalyst so acquired may be contacted with a methane gas to obtain stable conversion values over extended reaction times.

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