Catalyst regeneration process including metal contaminants...

B - Operations – Transporting – 01 – J

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252/1.D

B01J 23/90 (2006.01) B01J 23/94 (2006.01) C10G 1/08 (2006.01)

Patent

CA 1183116

ABSTRACT Spent catalysts removed from a catalytic hydrogenation process for hydrocarbon feedstocks, and containing undesired metals contaminants deposits, are regenerated. Following solvent washing to remove process oils, the catalyst is treated either with chemicals which form sulfate or oxy- sulfate compounds with the metals contaminants, or with acids which remove the metal contaminants, such as 5-50 W % sulfuric acid in aqueous, solution and 0-10 W % ammonium ion solutions to substantially remove the metals deposits. The acid treating occurs within the temperature range of 60-250°F for 5-120 minutes at substantially atmospheric pressure. Carbon deposits are removed from the treated catalyst by carbon burnoff at 800-900°F temperature, using 1-6 V % oxygen in an inert gas mixture, after which the regenerated catalyst can be effectively reused in the cata- lytic process.

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