Catalyst system and process for producing ethanol using said...

Details Catalyst system and process for producing ethanol using said... Catalyst system and process for producing ethanol using said...

B - Operations, Transporting

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260/639, 252/81

B01J 31/20 (2006.01) B01J 31/26 (2006.01) C07C 29/00 (2006.01) C07C 29/32 (2006.01) C07C 31/08 (2006.01)

Patent

CA 1162180

NOVEL CATALYST SYSTEM AND PROCESS FOR PRODUCING ETHANOL USING SAID NOVEL CATALYST SYSTEM ABSTRACT A novel catalyst system comprising (1) a cobalt car- bonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (2) a tertiary organo Group VA compound of the Periodic Table, (3) an iodine compound and (4) a ruthenium com- pound and to a process for selectively producing ethanol which comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide, (4) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material con- vertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (5) a tertiary organo Group VA compound of the Periodic Table, (6) an iodine compound and (7) a ruthenium compound and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to ethanol.

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