Catalyst system for moisture cure of ethylene-vinylsilane...

C - Chemistry – Metallurgy – 08 – K

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C08K 5/42 (2006.01) C08K 5/56 (2006.01)

Patent

CA 2747898

Ethylene-vinylsilane copolymers are moisture-cured under ambient conditions using a synergistic combination of at least one Lewis acid and at least one Bronsted acid or at least one Lewis base and at least one Bronsted base. Preferably the catalyst system comprises a Lewis acid, e.g., dibutyltin dilaurate, in combination with a Bronsted acid, e.g., sulfonic acid. The Lewis acid or base and the Bronsted acid or base is present in the catalyst system at a molar ratio of Lewis acid/base to Bronsted acid/base of 1:10 to 10:1.

Selon l'invention, des copolymères d'éthylène-vinylsilane sont durcis par hydratation dans des conditions ambiantes au moyen d'une combinaison synergique d'au moins un acide de Lewis et d'au moins un acide de Brønsted ou d'au moins une base de Lewis et d'au moins une base de Brønsted. De préférence, le système catalytique comprend un acide de Lewis, par exemple, dilaurate de dibutylétain, en combinaison avec un acide de Brønsted, par exemple l'acide sulfonique. L'acide ou la base de Lewis et l'acide ou la base de Brønsted sont présents dans le système catalytique en un rapport molaire acide/base de Lewis sur acide/base de Brønsted de 1:10 à 10:1.

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