Catalyst system for olefin polymerization and method for...

C - Chemistry – Metallurgy – 08 – F

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252/107, 402/645

C08F 4/64 (2006.01) C08F 10/00 (2006.01)

Patent

CA 1138409

ABSTRACT OF THE DISCLOSURE The invention concerns a catalyst system comprising (A) a halogen compound of trivalent titanium, (B) an organo- aluminum compound of the formula, R3-(m+n)AlYmXn wherein Y is a group having at least one of oxygen, nitrogen, sulfur and phosphorus atoms linked to the aluminum atom, R is a hydrogen atom, an alkyl group having 1 to 18 carbon atoms, an alkenyl group having 2 to 18 carbon atoms, a cycloalkyl group having 3 to 18 carbon atoms, an aryl group having 6 to 18 carbon atoms, or an aralkyl group having 7 to 18 carbon atoms, X is a halogen atom, and m and n are numbers satisfying the equations, 0 < m < 1, 0 ? n < 2, 0 < m+n ? 2, and (C) an electron-donor. The invention also concerns a method for producing olefin polymers which comprises polymerizing olefins in the presence of the catalyst system defined above. According to this method, highly crystalline olefin polymers having a broad molecular weight distribution can be produced, these polymers being particularly useful for extrusion molding and blow molding.

354380

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