Catalyst systems containing dimethylamino ether mono-ols for...

C - Chemistry – Metallurgy – 08 – G

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403/26, 403/35

C08G 18/24 (2006.01) C08G 18/18 (2006.01) C08G 18/28 (2006.01)

Patent

CA 1079449

ABSTRACT OF THE DISCLOSURE Cellular urethane polymers are provided by effect- ing the reaction of an organic polyol reactant comprising a polyether polyol and an organic polyisocyanate reactant in the presance of a blowing agent and a catalyst system com- prising a tertiary-dimethylamino ether mono-ol. In the dimethylamino ether mono-ols employed as catalysts in the practice of the invention, the tertiary-dimethylamino group and the hydroxyl group are positioned beta to a common acyclic ether oxygen atom or to different acyclic ether oxygen atoms which in turn are positioned beta to one another. The said dimethylamino ether mono-ols are versatile, low odor catalysts and are useful in forming cellular urethane polymers ranging from all water-blown flexible polyether foam to all fluorocarbon-blown rigid foam including semi-flexible and high-resilience foam products. Especially preferred for use in the practice of the invention are 2-(2-dimethylaminoethoxy)ethanol and 2-[2-(2-dimethylaminoethoxy)ethoxy]ethanol either as such or in combination with other catalysts including other tertiary-amine components and/or organic compounds of tin. Also provided are blended catalyst systems comprising said dimethylamino ether mono-ols. 1.

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