B - Operations – Transporting – 01 – J
Patent
B - Operations, Transporting
01
J
252/70
B01J 23/85 (2006.01) B01J 23/89 (2006.01) B01J 37/20 (2006.01) C10G 45/08 (2006.01)
Patent
CA 1298828
CATALYSTS FOR THE HYDRODENITROGENATION OF ORGANIC MATERIALS ABSTRACT OF THE INVENTION The present invention discloses a process for forming a catalyst for the hydrodenitrogenation of an organic feedstock, which includes (a) obtaining a precatalyst comprising cobalt and molybdenum or nickel and molybdenum; (b) adding in a non-oxidizing an atmosphere selected from hydrogen, helium, nitrogen, neon, argon, carbon monoxide or mixtures thereof to the precatalyst of step (a), a transition metal moiety selected from compounds of iridium, rhodium, iron, ruthenium, tungsten or mixtures thereof for a time and at a temperature effective to chemically combine the components: and (c) heating the chemically combined catalyst of step (b) optionally in vacuum to remove residual volatile organic materials. Preferably, a precatalyst of cobalt/molybdenum or alumina is heated between 100° and 500°C in a hydrogen atmosphere with an organometallic moiety of ruthenium, preferably ruthenium carbonyl. The invention further includes the catalysts obtained and the process of hydrodenitrogenation of organic feedstocks including a crude petroleum residue, a petroleum fraction, an oil shale fraction, a tar sands fraction, a coal derived powder, a coal derived liquid or mixtures thereof: The process reduces the amount of hydrogen usually needed to obtain hydrodenitrogenation and more selectively produces aromatic product than saturated organic product.
545231
Hirschon Albert S.
Laine Richard M.
Wilson Robert B. Jr.
Gowling Lafleur Henderson Llp
Hirschon Albert S.
Laine Richard M.
Sri International
Wilson Robert B. Jr.
LandOfFree
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