Catalysts for the isomerization of hydrocarbons, a process...

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B01J 23/40 (2006.01) B01J 23/10 (2006.01) B01J 23/63 (2006.01) B01J 27/08 (2006.01) B01J 37/24 (2006.01) C07C 5/22 (2006.01) C07C 5/27 (2006.01)

Patent

CA 1065295

ABSTRACT OF THE DISCLOSURE Isomerization catalysts for hydrocarbons, and particul- arly for normal paraffins and/or naphthenes are formed of at least one platinum-group metal, preferably platinum; at least one element : selected from the group consisting of rare earths and yttrium; at least one metal halide, for example aluminum trichloride; and a carrier for the foregoing metals and halide which is formed in whole or in part of at least one refractory mineral oxide, such as alumina, and additionally a halogen in combined form, preferably chlorine; the catalysts being prepared by at least one impregnation of the carrier with at least one solution containing at least one of the elements yttrium, rare earths, and platinum-group metals; at least one of the impregnating solutions including ions of the foregoing elements except the platinum-group metals; and an after- treatment by known means with at least metal halide, preferably selected from the group consisting of aluminum trichloride, alum- inum tribromide, ferric chloride, ferric bromide, beryllium di- chloride, and zinc dichloride, further modifications of the pro- cess including acidification with hydrochloric acid, calcination of the deposited metals, adjustment of the halogen content, and elimination of excess metal halide not fixed on the catalyst.

232935

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