Catalysts with low concentration of weak acid sites and...

B - Operations – Transporting – 01 – J

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B01J 29/035 (2006.01) C01B 37/02 (2006.01) C07C 2/66 (2006.01) C07C 15/073 (2006.01)

Patent

CA 2344293

Ethylbenzene is produced by alkylation over monoclinic silicalite catalysts having a weak acid site concentration of less than 50 micromoles per gram. A feedstock containing benzene and ethylene is applied to an alkylation reaction zone having at least one catalyst bed containing a monoclinic silicalite catalyst having a weak acid site concentration of less than 50 micromoles per gram. The alkylation reaction zone is operated at temperature and pressure conditions in which the benzene is in a gaseous phase to cause gas- phase alkylation of the aromatic substrate in the presence of the silicalite catalysts to produce an alkylation product. The alkylation product is then withdrawn from the reaction zone for separation and recovery.

De l'éthylbenzène est produit par alkylation sur des catalyseurs de silicalite monoclinique ayant une concentration de sites d'acide faible de moins de 50 micromoles par gramme. Une charge d'alimentation contenant du benzène et de l'éthylène est envoyée dans une zone de réaction d'alkylation dans laquelle se trouve au moins un lit de catalyseur contenant le catalyseur de silicalite monoclinique ayant une concentration de sites d'acide faible de moins de 50 micromoles par gramme. La zone de réaction d'alkylation fonctionne dans des conditions de température et de pression pour lesquelles le benzène est en phase gazeuse pour provoquer une alkylation en phase gazeuse du substrat aromatique en présence des catalyseurs de silicalite et produire un produit d'alkylation. Ce dernier est retiré de la zone de réaction afin de le séparer et de le récupérer.

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