Catalytic conversion of gases via cation-exchangeable...

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B01D 53/86 (2006.01) B01D 53/04 (2006.01) B01D 53/88 (2006.01) B01J 29/06 (2006.01) B01J 29/70 (2006.01)

Patent

CA 2294394

A process for catalytic conversion and/or adsorption of gases inclusive of NOx, SOx, CO2, CO, dioxins and PAHs and combinations thereof wherein said gases may contain particulates which include contacting one or more of such gases with an alumino-silicate material having: (i) a primarily tetrahedrally co-ordinated aluminium as established by the fact that the 27Al Magic Angle Spinning (MAS) provides a single peak at 55-58 ppm (FWHM = 23 ppm) relative to Al(H2O)63+; and (ii) a cation exchange capacity of at least 1 meq 100 g-1 in aqueous solution at room temperature.

L'invention concerne un procédé de conversion catalytique et/ou d'absorption de gaz, dont NOx, SOx, CO¿2?, CO, les dioxines, les PAH et des combinaisons de ceux-ci, lesdits gaz pouvant contenir des particules. Ledit procédé consiste à mettre un ou plusieurs desdits gaz en contact avec une matière alumino-silicate ayant: (i) un aluminium coordonné principalement de manière tétraédrique, conformément au fait que le Magic Angle Spinning Al?27¿ (MAS) produit un pic unique à 55-58 ppm (LMII = ?23 ppm) par rapport à Al(H¿2?O)¿6??3+¿; et (ii) une capacité d'échange d'ions d'au moins 1 meq 100 g?-1¿ en solution aqueuse, à la température ambiante.

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