Catalytic generation of hydrogen from hydrocarbons

C - Chemistry – Metallurgy – 01 – B

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23/315, 23/401

C01B 3/40 (2006.01) B01J 8/02 (2006.01) B01J 23/652 (2006.01) C01B 3/36 (2006.01) C01B 3/38 (2006.01)

Patent

CA 1290549

- 20 - ABSTRACT A catalytic process for the generation of hydrogen by the partial oxidation of hydrocarbons, especially alkanes such as methane or hexane. The preferred catalyst system comprises from 0.01 to 5wt% platinum and from 1 to 15wt% chromium oxide supported on a refractory solid such as silica. Also a reactor for effecting the process in which the reactants are injected into or amongst the catalyst system and a technique for starting the process at ambient temperature by introducing an initiating compound such as methanol into the catalyst system.

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