Catalytic oxidation/decarbonylation of polynuclear aromatic...

C - Chemistry – Metallurgy – 07 – C

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260/236.2, 260/6

C07C 50/18 (2006.01) C07C 1/207 (2006.01) C07C 15/04 (2006.01) C07C 46/04 (2006.01)

Patent

CA 1118797

ABSTRACT OF THE DISCLOSURE This invention provides processes for the production of benzene from anthracene, 9, 10-anthraquinone from anthracene, and benzene from 9, 10-anthraquinone. In the conversion of anthracene to 9, 10-anthraquinone, anthracene }s reacted with a molecular oxygen-containing gas (e.g., air) in the presence.- of a catalyst and promotor at an elevated temperature (65° to 205°C). To convert 9, 10-anthraquinone to benzene, the anthra- quinone is thermally- cracked, with or without a suitable catalyst, at a temperature of at least 425°C. An example of a suitable catalyst is synthetic zeolite.

344798

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