Catalytic oxidation of liquid cycloparaffins

Details Catalytic oxidation of liquid cycloparaffins Catalytic oxidation of liquid cycloparaffins

C - Chemistry, Metallurgy

07

C

260/582, 260/524

C07C 35/02 (2006.01) B01J 31/18 (2006.01) C07C 29/50 (2006.01) C07C 45/33 (2006.01) C07C 49/385 (2006.01) C07C 51/31 (2006.01)

Patent

CA 1196018

Abstract of the Disclosure A process for the catalytic oxidation of liquid cycloparaffins to oxidation products thereof is disclosed. In the process partial oxidation products are formed by oxi- dizing the cycloparaffin with molecular oxygen-containing gas in the presence of an oxidation catalyst comprising two heavy metal compounds. The first heavy metal compound is a cobalt compounds. The first heavy metal compound is a phate, dicycloalkylphosphate and alkylcycloalkphophate, optionally additionally combined with pyridine. The second heavy metal compound is a chromium alkanoate. A preferred catalyst is cobalt bis[di(2-ethythexyl)phosphate] combined with chromium naphthenate.

401920

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