Catalytic preparation of tertiary butyl alcohol from...

Details Catalytic preparation of tertiary butyl alcohol from... Catalytic preparation of tertiary butyl alcohol from...

C - Chemistry, Metallurgy

07

C

260/637, 252/82

C07C 29/50 (2006.01) C07C 29/132 (2006.01) C07C 31/12 (2006.01)

Patent

CA 2033935

CATALYTIC PREPARATION OF TERTIARY BUTYL ALCOHOL FROM TERTIARY BUTYL HYDROPEROXIDE (Docket No. 80,684-F) ABSTRACT OF THE DISCLOSURE A tertiary butyl hydroperoxide feedstock, such as one prepared from the reaction product formed by the reaction of isobutane with molecular oxygen and which feedstock comprises tertiary butyl hydroperoxide dissolved in tertiary butyl alcohol, is charged to a catalytic decomposition zone where the tertiary butyl hydroperoxide is catalytically decomposed in the presence of a soluble catalyst system to provide a decomposition reaction product characterized by a high conversion rate and a high selectivity of tertiary butyl hydroperoxide to tertiary butyl alcohol, the catalyst system being composed of a soluble iron compound and a soluble ruthenium compound.

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