Catalytic process for converting hydro-carbonaceous feeds,...

Details Catalytic process for converting hydro-carbonaceous feeds,... Catalytic process for converting hydro-carbonaceous feeds,...

C - Chemistry, Metallurgy

07

C

C07C 305/06 (2006.01) C07C 1/20 (2006.01) C07C 1/36 (2006.01) C07C 11/02 (2006.01) C07C 29/48 (2006.01) C07C 29/50 (2006.01) C07C 67/035 (2006.01) C07C 203/04 (2006.01) C07C 303/24 (2006.01) C07C 303/26 (2006.01) C07C 303/28 (2006.01) C07C 309/65 (2006.01) C07C 391/00 (2006.01) C07F 9/11 (2006.01)

Patent

CA 2103789

2103789 9214738 PCTABS00015 This invention is a process for converting hydrocarbonaceous feeds, particularly lower alkanes, into their corresponding esters and optionally into various intermediates (such as alcohols) and optionally into liquid hydrocarbons. The hydrocarbonaceous feeds are oxidatively converted to oxy-esters at high selectivity and conversion and at practical reaction rates using at least catalytic amounts of certain class "B" metals and/or metal ions defined by the Pearson definition as "soft" or "borderline". Desirable catalysts comprise such metals as Pd, Tl, Pt, Hg, and Au. Mercury is most desired. If so desired, the oxy-esters may be converted to alcohols or other intermediates such as halides. The oxy-esters, alcohols, and other intermediates may optionally be converted to liquid hydrocarbons such as gasoline.

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