Catalytic process for polyhydric alcohols and derivatives

Details Catalytic process for polyhydric alcohols and derivatives Catalytic process for polyhydric alcohols and derivatives

C - Chemistry, Metallurgy

07

C

260/383, 260/632

C07C 29/00 (2006.01) B01J 31/20 (2006.01) B01J 31/24 (2006.01) C07C 29/151 (2006.01) C07C 29/158 (2006.01) C07C 41/01 (2006.01) C07C 67/36 (2006.01) C07F 15/00 (2006.01)

Patent

CA 1046073

Abstract of the Disclosure This invention relates to the manufacture of such valuable chemicals as polyhydric alcohols, their ether and ester derivatives, oligomers of such alcohols and monohydric alcohols and their ether and ester derivatives by reacting oxides of carbon and hydrogen in the presence of a bis(triorgano phosphine)iminium cation and a rhodium carbonyl com- plex provided to the reaction as a rhodium carbonyl cluster anion which possesses an infrared spectrum which exhibits three intense wavelength bands between about plus and minus 10 cm-1 of about 1868 cm-1, about 1838 cm-1, and about 1785 cm-1 at a pressure of at least about 500 pounds per square inch absolute.

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