C - Chemistry – Metallurgy – 07 – F
Patent
C - Chemistry, Metallurgy
07
F
C07F 15/02 (2006.01) C07C 37/00 (2006.01) C07C 37/08 (2006.01) C07C 39/04 (2006.01) C07C 45/53 (2006.01) C07C 49/403 (2006.01) C07C 407/00 (2006.01) C07C 409/02 (2006.01) C07C 409/08 (2006.01) C07C 409/10 (2006.01) C07C 409/14 (2006.01) C07F 5/00 (2006.01) C07F 13/00 (2006.01) C07F 15/04 (2006.01) C07F 15/06 (2006.01)
Patent
CA 2250743
A method is provided for preparing organic hydroperoxides by oxidizing aryl alkyl hydrocarbons having a benzylic hydrogen with an oxygen containing gas using as a catalyst an oxo (hydroxo) bridged tetranuclear metal complex having a mixed metal core, one metal of the core being a divalent metal selected from Zn, Cu, Fe, Co, Ni, Mn or mixtures thereof and another metal being a trivalent metal selected from In, Fe, Mn, Ga, and Al. A method is also provided for the manufacture of the catalyst.
Technique de préparation d'hydroperoxydes organiques par oxydation d'arylalkyl-hydrocarbures possédant un hydrogène benzylique avec du gaz contenant de l'oxygène, en employant comme catalyseur un complexe métallique tétranucléaire à pont oxo(hydroxo) ayant un noyau métallique mixte, un métal du noyau étant un métal bivalent choisi parmi Zn, Cu, Fe, Co, Ni, Mn ou des mélanges de ceux-ci, un autre métal étant un métal trivalent choisi parmi In, Fe, Mn, Ga et Al. L'invention porte aussi sur une technique d'obtention du catalyseur.
Bond Jeffrey E.
Dakka Jihad M.
Gorun Sergiu M.
Schriver George W.
Stibrany Robert T.
Borden Ladner Gervais Llp
Exxon Chemical Patents Inc.
Exxon Research And Engineering Company
Exxonmobil Chemical Patents Inc.
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