Catalytic reduction of nox and carbon monoxide using methane...

B - Operations – Transporting – 01 – D

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B01D 53/34 (2006.01) B01D 53/94 (2006.01) B01J 29/06 (2006.01) F01N 3/20 (2006.01) F01N 13/02 (2010.01) F01N 7/02 (2006.01)

Patent

CA 2077202

ABSTRACT The invention describes a process for catalytically destroying NOx and carbon monoxide present in oxygen-containing combustion products wherein methane serves as a reductant. The process comprises combusting a fuel source inthe presence of oxygen to form combustion product comprising nitrogen oxides, carbon monoxide and oxygen; introducing methane into the combustion products in an amount such that the total amount of methane to nitrogen oxides present, expressed as a ratio, by volume is greater than about 0.1; and reacting the nitrogen oxides, carbon monoxide, methane and oxygen in the presence of an exchanged crystalline zeolite under conditions sufficient to convert the nitrogen oxides and carbon monoxide to gaseous nitrogen, water and carbon oxides. Suitable catalystsinclude zeolites having a silicon to aluminum ratio of greater than or equal to about 2.5 which zeolites are exchanged with a cation selected from the group consisting of gallium, niobium, cobalt, nickel, iron, chromium, rhodium and manganese.

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