Catalytic system for epoxidation of alkenes

Details Catalytic system for epoxidation of alkenes Catalytic system for epoxidation of alkenes

B - Operations, Transporting

01

J

260/372, 252/85

B01J 23/50 (2006.01) C07C 27/12 (2006.01) C07D 301/10 (2006.01)

Patent

CA 1290313

Abstract: A process is provided for epoxidation of an alkene in the presence of an oxygen-containing gas which comprises contacting the alkene and the oxygen- containing gas under epoxidation conditions in the presence of at least one gaseous efficiency-enhancing member of a redox-half reaction pair and a supported silver catalyst, the catalyst comprising a cata- lytically effective amount of silver on a solid por- ous support having a stability-enhancing morphology and an efficiency-enhancing amount of at least one efficiency-enhancing salt of a member of a redox-half reaction pair, the support having a surface area of at least about 0.7 m2/g and a particulate matrix which contains particles having at least one substan- tially flat major surface.

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