Catalytic system for epoxidation of alkenes employing low...

C - Chemistry – Metallurgy – 07 – D

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260/372, 252/85

C07D 301/10 (2006.01) B01J 23/50 (2006.01) B01J 32/00 (2006.01)

Patent

CA 1293496

Abstract: A process is provided for the epoxidation of an alkene in the presence of an oxygen-containing gas which comprises contacting the alkene and the oxygen- containing gas under epoxidation conditions in the presence of at least one efficiency-enhancing gaseous member of a redox-half reaction pair and a solid catalyst, the catalyst comprising a catalytically- effective amount of silver on a solid support and an efficiency-enhancing amount of at least one efficien- cy-enhancing salt of a member of a redox-half reac- tion pair, the support having less than about 50 ppm, by weight, of leachable sodium.

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