Cationic polymerization process

C - Chemistry – Metallurgy – 08 – F

Patent

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252/116, 402/403

C08F 4/14 (2006.01) B01J 27/16 (2006.01) C08F 2/04 (2006.01) C08F 36/04 (2006.01)

Patent

CA 1129148

26,469 ABSTRACT OF THE DISCLOSURE There is provided a process for cationically polymerizing piperylene batchwise or continuously by the addition of piperylene either alone or in admixture with a minor amount of at least another hydrocarbon monomer, incrementally, to a catalyst system consisting essentially of a major amount of an aluminum halide and a minor amount of an inorganic phosphorus acid in an inert solvent while controlling the temperature of reaction in the range of 0°C. to 50°C., drowning the polymerization mixture in water, separating the organic phase therefrom, then removing the solvent and recovering a solid polymer in good color and yield, free from an intractable gel, rendering the same useful as a tackifying resin.

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