Cationic polymerization process

C - Chemistry – Metallurgy – 08 – F

Patent

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252/113, 402/580

C08F 4/20 (2006.01) C08F 10/14 (2006.01) C08F 32/08 (2006.01)

Patent

CA 1087154

ABSTRACT OF THE DISCLOSURE There is provided a process for cationally polymer- izing or co-polymerizing batchwise or continuously .alpha.-pinene by adding .alpha.-pinene either alone or in admixture with other ter- pene monomers, incrementally to a catalyst system comprising an aluminum halide and an antimony halide in the presence or absence of a (lower)alkyl, alkenyl or aralkyl halide in an in- ert solvent while controlling the temperature of reaction in the range of -30°C. to +30°C., drowning the polymerization mixture in water, separating the organic phase therefrom, re- moving the solvent therefrom and recovering a solid polymer in good yield.

269317

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