Cationic transition-metal arene catalysts

Details Cationic transition-metal arene catalysts Cationic transition-metal arene catalysts

C - Chemistry, Metallurgy

07

F

C07F 15/00 (2006.01)

Patent

CA 2760386

Disclosed are cationic ruthenium arene complexes of Formula (I): [Ru(D-Z1-NHR1)(Ar)(LB)n]r+ [Y-]r wherein Ar is optionally substituted aryl, D-Z1-NHR1 is a coordinated bidentate ligand wherein D, Z1, R1 and R2 are as defined herein, and where R1 and Ar, or R2 and Ar may be linked together, n is 0 or 1, r is 1 or 2, LB is a neutral Lewis base, and Y is a non-coordinating anion. The complexes are active catalysts for reduction reactions, including the transfer-hydrogenation of carbon-oxygen (C=O) and carbon-nitrogen (C=N) double bonds.

L'invention concerne des complexes arène-ruthénium cationiques représentés par la formule I, [Ru(D-Z1-NHR1)(Ar)(LB)n]I+[Y-]r dans laquelle Ar est éventuellement substitué aryle, D-Z1-NHR1 est un ligand bidentate coordonné dans lequel D, Z1, R1 et R2 sont tels que définis dans la description, et dans laquelle R1 et Ar, ou R2 et Ar peuvent être liés ensemble, n est 0 ou 1, r est 1 ou 2, LB est une base de Lewis neutre, et Y est un anion de non coordination. Les complexes sont des catalyseurs actifs pour des réactions de réduction, notamment l'hydrogénation par transfert de liaisons doubles carbone-oxygène (C=O) et carbone -azote (C=N).

Affiliated with

Also associated with

Rating

Cationic transition-metal arene catalysts does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Cationic transition-metal arene catalysts, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Cationic transition-metal arene catalysts will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFCA-PAI-O-1820846