Ceramic materials from silazane polymers

C - Chemistry – Metallurgy – 04 – B

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C04B 35/56 (2006.01) C04B 35/571 (2006.01) C04B 35/58 (2006.01) C04B 35/589 (2006.01) C08K 3/38 (2006.01)

Patent

CA 1241972

CERAMIC MATERIALS FROM SILAZANE POLYMERS ABSTRACT A method is disclosed for increasing the ceramic yield of a ceramic material obtained by firing a R3SiNH- containing silazane polymer to an elevated temperature in an inert atmosphere or in a vacuum. The method involves adding certain boron compounds to the R3SiNH-containing silazane polymer prior to firing. Suitable boron compounds include, among others, metaboric acid, orthoboric acid, and organo- boron compounds of the general formula BR? where R" is selected from the group consisting of alkyl radicals containing 1 to 5 carbon atoms, phenyl radicals, and -OR''' radicals where R''' is an alkyl radical containing 1 to 4 carbon atoms.

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