Chalk-resistant, medium to dark colored polyurethanes,...

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

400/102, 403/17,

C08G 18/00 (2006.01) C08G 18/63 (2006.01) C08K 5/56 (2006.01)

Patent

CA 1082381

ABSTRACT OF THE DISCLOSURE Improvements in polymer/polyol compositions which are convertible by reaction with polyisocyanates to poly- urethanes which are pigmented to a medium to dark color and which inherently chalk upon exposure to weather and wherein the polymer of the polymer/polyol composition is dispersed in the polyol thereof and is formed from one or more poly- merizable ethylenically unsaturated monomers. The improve- ment provides to said polyurethanes resistance to chalking on exposure to weather and in one embodiment comprises the presence, in the polymer/polylol compositions used to make the polyurethanes, of a metallocene from the class consisting of ferrocene, ferrocene derivatives, cobaltocene and nickel- ocene in an amount effective to provide chalk resistance. Optionally, the metallocene can be present in the polyiso- cyanate composition instead of the polymer/polyol composition. Improved dark colored polyurethanes are made by reacting a mixture comprising (a) a polymer/polyol composition and (b) an organic polyisocyanate in the presence of (c) a catalyst for the reaction of (a) and (b), (d) a metallocene, preferably ferrocene, or a ferrocene polymer and (a) a medium to dark pigment to produce the polyurethane.

282630

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