Chemiluminescent 1,2-dioxetanes

C - Chemistry – Metallurgy – 07 – F

Patent

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Details

C07F 9/06 (2006.01) C07C 43/166 (2006.01) C07C 43/168 (2006.01) C07C 43/178 (2006.01) C07D 321/00 (2006.01) C07F 7/08 (2006.01) C07F 9/12 (2006.01) C07F 9/655 (2006.01) C07K 17/02 (2006.01) G01N 33/533 (2006.01)

Patent

CA 2342979

Chemiluminescent 1,2-dioxetanes derived from substituted aromatic esters or ketones and spiro-fused ketones with either .pi.-electron system in the ring or with carbon-carbon double bond or triple bond(s) in the spiro-fused ring are provided herein. These 1,2-dioxetanes have electron donating or withdrawing groups at the four-membered peroxide ring, thus, the 1,2- dioxetanes ring hereof is affected by the added electronic charge.

L'invention concerne des 1,2-dioxétanes chimioluminescents dérivés d'esters ou de cétones aromatiques substitués et de cétones spiro-condensées avec un système d'électrons .pi. dans le noyau ou avec des liaisons doubles ou triples carbone-carbone dans le noyau spiro-condensé. Ces 1,2-dioxétanes possèdent des groupes donnant ou retirant des électrons au noyau peroxyde à quatre chaînons et ainsi, le noyau 1,2-dioxétanes est affecté par la charge électronique ajoutée.

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