C - Chemistry – Metallurgy – 07 – F
Patent
C - Chemistry, Metallurgy
07
F
C07F 17/02 (2006.01) B01J 31/16 (2006.01) B01J 31/22 (2006.01) C07B 53/00 (2006.01) C07C 231/12 (2006.01) C07C 233/47 (2006.01) C07D 307/33 (2006.01)
Patent
CA 2263715
The invention relates to chiral ferrocenyls of formula (I), wherein R a is -P(R10R11) or -SR12; R b is -P(R'10R'11), -SR'12, -CH=NR12, -CH2-NH-R12 or -CH2-O-P(R10R11); and the other substituents are as defined in claim 1, which may be used as ligands for transition metal catalysts in enantioselective reactions.
L'invention concerne des ferrocényles chiraux de la formule (I) dans laquelle Ra représente -P(R10R11) ou -SR12, Rb représente -P(R'10R'11), -SR'12, -CH=NR12, -CH2-NH-R12 ou -CH2-O-P(R10R11), ainsi que les autres substituants tels que mentionnés dans la revendication 1. On peut utiliser ces composés en tant que ligands destinés à des catalyseurs métalliques de transition, dans des réactions énantiosélectives.
Landert Heidi
Pioda Giorgio
Pugin Benoit
Fetherstonhaugh & Co.
Novartis Ag
Syngenta Participations Ag
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