Chiral synthesis of tertiary alcohols with a hydrolase

Details Chiral synthesis of tertiary alcohols with a hydrolase Chiral synthesis of tertiary alcohols with a hydrolase

C - Chemistry, Metallurgy

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C12P 41/00 (2006.01) C07C 29/88 (2006.01) C07C 29/92 (2006.01) C07C 67/48 (2006.01) C07D 249/08 (2006.01) C07D 521/00 (2006.01) C12P 17/02 (2006.01) C12P 17/10 (2006.01)

Patent

CA 2160015

Method of preparing an optically active compound of formula (I), wherein R and R1 are independently alkyl, alkenyl, alkynyl, alkoxy, alkoxyalkyl, cycloalkyl, axyl, aralkyl, a heterocyclic group or a C1-C4 alkyl- heterocycte, each being optionally substituted, provided that R and R1 are not identical and * is an optically active chiral centre, from the corresponding racemic ester or diol by treating with a hydrolase enzyme.

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