Chiral tridentate compounds, corresponding organometal...

C - Chemistry – Metallurgy – 07 – D

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C07D 215/12 (2006.01) C07F 9/50 (2006.01)

Patent

CA 2702859

The invention relates to a compound of the formula (I) or the formula (II) in which: W is an oxygen atom or a radical of the formula NH; X is hydrogen or an alkaline cation or a C1-C8 alkyl or a -(CH 2) a3 - C(R4 )(R5 )(R6 ) radical; X and R on the one hand and X and Rl on the other hand may independently form an optionally substituted cycle with 5, 6 or 7 links. The invention also relates to complexes of said compounds with at least one metal selected from the group comprising copper, palladium, ruthenium, iridium and rhodium, and to a method for the synthesis of these compounds. These compounds and complexes can be used in various asymmetrical catalysis methods.

Composé de formule (I) ou de formule (II) dans lesquelles: W est un atome d'oxygène ou un radical de formule NH; X est un hydrogène, ou un cation alcalin, ou un alkyl en C1 à C8, ou un radical -(CH 2) n 3 - C(R4 )(R5 )(R6 ); X et R d'une part et X et R1 d'autre part pouvant former indépendamment un cycle à 5, 6 ou 7chaînons éventuellement substitué. L'invention concerne aussi des complexes de tels composés avec au moins un métal choisi dans le groupe constitué par le cuivre, le palladium, le ruthénium, l'iridium et de rhodium, ainsi qu'un procédé de synthèse de tels composés. De tels composés et complexes sont susceptibles d'être utilisés dans le cadre de divers procédés de catalyse asymétrique.

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