Circulation process for the production of aliphatic and...

C - Chemistry – Metallurgy – 07 – C

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260/456.3

C07C 263/04 (2006.01) C07C 265/14 (2006.01)

Patent

CA 1318683

ABSTRACT OF THE DISCLOSURE A circulation process for the production of (cyclo)aliphatic diisocyanates, in which the biscarbamate is produced from diamines, by-products from the thermal cracking, urea, and alcohol in the presence of N-unsubstituted carbamates and dialkyl carbonates, and with separation of NH3; the subsequent cracking of the biscarbamate is carried out in the liquid phase without solvent; the diisocyanate and alcohol are condensed; the diisocyanate is subjected to a purifying distillation; and a portion of the cracking reaction mixture is discharged with the by-products formed and recycled to the biscarbamate production step after prior reaction with the crude alcohol formed, effectively utilizes the by-products formed in the cracking step and is an industrially practical and economical process.

608074

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