(co)polymerization process in suspension for preparing...

C - Chemistry – Metallurgy – 08 – F

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Details

C08F 214/18 (2006.01) C08F 2/14 (2006.01) C08F 4/34 (2006.01) C08F 4/36 (2006.01) C08F 14/18 (2006.01) C08F 210/00 (2006.01)

Patent

CA 2144891

The invention relates to a (co)polymerization process in suspension for preparing hydrogen containing thermoplastic fluoropolymers, such as for instance ethylene/chlorotrifluoro- ethylene or ethylene/tetrafluoroethylene copolymers, or vinylidenefluoride homopolymers or copolymers, wherein bis- dichlorofluoroacetylperoxide (CFCl2-CO-O)2 (DCFAP) is used as polymerization initiator. From such process products endowed with high thermal stability, remarkably higher than that obtainable using bis-trichloroacetylperoxide (TCAP), are obtained.

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