Co-production of 2-alkanones and phenols

Details Co-production of 2-alkanones and phenols Co-production of 2-alkanones and phenols

C - Chemistry, Metallurgy

07

C

260/621, 260/587

C07C 39/02 (2006.01) C07C 2/66 (2006.01) C07C 37/08 (2006.01) C07C 45/53 (2006.01) C07C 49/04 (2006.01)

Patent

CA 1144567

ABSTRACT A process for the co-production of 2-alkanones having at least five carbon atoms and phenol or a substituted phenol. In the first step, benzene or a substituted benzene is alkylated with an alkyl moiety of at least five carbon atoms to selectively produce the 2-arylalkane isomer. Subsequent oxidation to the hydroperoxide followed by its acid cleavage yields the desired products. The alkylation step is carried out in the presence of a selective crystalline zeolite having pore openings with a major dimension of six to seven Angstroms.

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