Coated, granular n-alkylammonium acetonitrile salts and...

C - Chemistry – Metallurgy – 11 – D

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C11D 17/00 (2006.01) C11D 3/39 (2006.01)

Patent

CA 2423607

The present invention relates to granular, coated N-alkylammoniumacetonitrile salts of the formula (I) R2R3NR1-CR4R5-CN+Y- (I) in which R1 is a C1-C24-alkyl group which may be interrupted by nonadjacent oxygen atoms or may additionally carry hydroxyl groups, a C4-C24-cycloalkyl group, a C7-C24-alkaryl group or a group of the formula -CR4R5-CN, R2 and R3 in each case independently of one another have the meaning of R1 or together are a saturated four- to nine-membered ring having at least one carbon atom and at least one further heteroatom from the group consisting of oxygen, sulfur and nitrogen, R4 and R5 in each case independently of one another are hydrogen, a C1-C24- alkyl group which may be interrupted by nonadjacent oxygen atoms or may additionally carry hydroxyl groups, a C4-C24-cycloalkyl group or a C7-C24-alkaryl group and Y is sulfate or hydrogensulfate anion in the corresponding stoichiometric amount, which are coated with a material which is chosen from the group consisting of organic, inorganic, hydrophilic and hydrophobic substances.

L'invention concerne des sels granuleux et enduits de N-alkylammoniumacétonitrile de formule générale (I) R<2>R<3>N R<1>-CR<4>R<5>-CN<+>Y<-> dans laquelle R<1> signifie un groupe alkyle C1 à C24, pouvant être interrompu par des atomes d'oxygène non voisins ou pouvant porter en plus des groupes hydroxyle, un groupe cycloalkyle C4 à C24, un groupe alkaryle C7 à C24, ou un groupe de formule CR<4>R<5>-CN, R<2> et R<3> ont chacun, indépendamment l'un de l'autre, la signification de R<1> ou, ensemble, dans l'atome d'azote auquel ils sont liés, désignent un anneau saturé de quatre à neuf chaînons avec au moins un atome C et au moins un autre hétéroatome du groupe oxygène, soufre et azote, R<4> et R<5> représentent chacun, indépendamment l'un de l'autre, hydrogène, un groupe alkyle C1 à C24, pouvant être interrompu par des atomes d'oxygène non voisins ou pouvant porter en plus des groupes hydroxyle, un groupe cycloalkyle C4 à C24 ou un groupe alkaryle C7 à C24, et Y signifie un anion de sulfate ou de sulfate d'hydrogène dans la quantité stoechiométrique correspondante. Ces éléments sont enduits d'un matériau sélectionné dans le groupe comprenant des substances organiques, inorganiques, hydrophiles et hydrophobes.

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